Metal Dihydrogen and -Bond Complexes: Structure, Theory and Reactivity by Gregor

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Metal Dihydrogen and -Bond Complexes

by Gregory J. Kubas

Covers Kubas' discovery of dihydrogen coordination and the study of its structure and general properties. This book also discusses both the theoretical beliefs and experimental results of bonding and activation of dihydrogen on metal centers and the coordination and activation of C-H, B-H, X-H, and X-Y bonds.

FORMAT Hardcover LANGUAGE English CONDITION Brand New

Publisher Description

This volume is an account of 20th-century work in the area of sigma complexation. It covers not only Kubas' discovery of dihydrogen coordination and the study of its structure and general properties, but also discusses both the theoretical beliefs and experimental results of bonding and activation of dihydrogen on metal centres and the co-ordination and activation of C--H, B--H, X--H, and X--Y bonds.

Table of Contents

Background and Discovery of Dihydrogen Coordination.- Synthesis and General Properties of Dihydrogen Complexes.- Bonding and Activation of Dihydrogen and ? Ligands: Theory versus Experiment.- Structural and NMR Studies of Dihydrogen Complexes.- Intramolecular Dynamics of Dihydrogen-hydride Ligand Systems: Hydrogen Rotation, Exchange, and Quantum-mechanical Effects.- Thermodynamics, Kinetics, and Isotope Effects of the Binding and Cleavage of ? Ligands versus Classical Ligands.- Vibrational Studies of Coordinated Dihydrogen.- Reactions and Acidity of Dihydrogen Complexes.- Activation of Hydrogen and Related Small Molecules by Metalloenzymes and Sulfur Ligand Systems.- Coordination and Activation of Si-H, Ge-H, and Sn-H Bonds.- C-H Bond Coordination and Activation.- Coordination and Activation of B-H and Other X-H and X-Y Bonds.

Review

`[This book] will remain a classic for researchers, professors, and students and a must for everyone working in organometallic Chemistry and Catalysis.'
Bruno Chaudret, Director de Recherche, Laboratoire de Chimie de Coordination
`This new book provides an excellent source of information on the formation, structures, and reactions of Metal Dihydrogen and sigma-Bond Complexes. The presentation is clear, comprehensive and up-to-date. This thorough and readable book should be on the shelves of scientific libraries and individual chemists interested in inorganic, catalytic and physical chemistry.'
D.F. Shriver, Morrison Professor of Chemistry, Northwestern University
`[An] excellent and comprehensive treatise...a true expert in the field of metal-hydrogen chemistry.'
John P. Fackler, Jr., Distinguished Professor of Chemistry, Texas A&M University
`The reactions of transition metals and metal complexes with hydrogen, and also hydrocarbons, were already very important fields of study with applications in large scale industrial catalysis and energy storage and conversion. These useful reactions are now viewed in a new light thanks to the emergence of the new concept of sigma-complex chemistry as described clearly and comprehensively by Greg Kubas in this book.'
Robert H. Morris, Professor of Chemistry, University of Toronto
`This book will be of use to persons whose research interests include the subject matter of the book, but I also recommend sections of it more broadly... I strongly recommend the book for those who are involved in the field. It is very well written...'
Ray L. Sweany, University of new Orleansin Journal of the American Chemical Society
`I strongly recommend the book for those who are involved in the field. It is very well written, and for those who are worried about the time delay between the onset of the writing and the publication, some references come from as late as the latter half of 2000'
J.AM.Chem. Soc., 124:14 (2002)

Long Description

According to R.H. Crabtree, Metal Dihydrogen and sigma-Bond Complexes is described as 'the definitive account of twentieth-century work in the area of sigma complexation'. It covers not only Kubas' discovery of dihydrogen coordination and the study of its structure and general properties but also discusses both the theoretical beliefs and experimental results of bonding and activation of dihydrogen on metal centers and the coordination and activation of C-H, B-H, X-H, and X-Y bonds, giving an overview of 'one of the hottest areas in chemistry'.

Review Text

' [This book] will remain a classic for researchers, professors, and students and a must for everyone working in organometallic Chemistry and Catalysis. ' Bruno Chaudret, Director de Recherche, Laboratoire de Chimie de Coordination ' This new book provides an excellent source of information on the formation, structures, and reactions of Metal Dihydrogen and sigma-Bond Complexes. The presentation is clear, comprehensive and up-to-date. This thorough and readable book should be on the shelves of scientific libraries and individual chemists interested in inorganic, catalytic and physical chemistry. ' D.F. Shriver, Morrison Professor of Chemistry, Northwestern University ' [An] excellent and comprehensive treatise...a true expert in the field of metal-hydrogen chemistry. ' John P. Fackler, Jr., Distinguished Professor of Chemistry, Texas A&M University ' The reactions of transition metals and metal complexes with hydrogen, and also hydrocarbons, were already very important fields of study with applications in large scale industrial catalysis and energy storage and conversion. These useful reactions are now viewed in a new light thanks to the emergence of the new concept of sigma-complex chemistry as described clearly and comprehensively by Greg Kubas in this book. ' Robert H. Morris, Professor of Chemistry, University of Toronto ' This book will be of use to persons whose research interests include the subject matter of the book, but I also recommend sections of it more broadly... I strongly recommend the book for those who are involved in the field. It is very well written... ' Ray L. Sweany, University of new Orleans in Journal of the American Chemical Society ' I strongly recommend the book for those who are involved in the field. It is very well written, and for those who are worried about the time delay between the onset of the writing and the publication, some references come from as late as the latter half of 2000 ' J.AM.Chem. Soc., 124:14 (2002)

Review Quote

'[This book] will remain a classic for researchers, professors, and students and a must for everyone working in organometallic Chemistry and Catalysis.' Bruno Chaudret, Director de Recherche, Laboratoire de Chimie de Coordination 'This new book provides an excellent source of information on the formation, structures, and reactions of Metal Dihydrogen and sigma-Bond Complexes. The presentation is clear, comprehensive and up-to-date. This thorough and readable book should be on the shelves of scientific libraries and individual chemists interested in inorganic, catalytic and physical chemistry.' D.F. Shriver, Morrison Professor of Chemistry, Northwestern University '[An] excellent and comprehensive treatise...a true expert in the field of metal-hydrogen chemistry.' John P. Fackler, Jr., Distinguished Professor of Chemistry, Texas A&M University 'The reactions of transition metals and metal complexes with hydrogen, and also hydrocarbons, were already very important fields of study with applications in large scale industrial catalysis and energy storage and conversion. These useful reactions are now viewed in a new light thanks to the emergence of the new concept of sigma-complex chemistry as described clearly and comprehensively by Greg Kubas in this book.' Robert H. Morris, Professor of Chemistry, University of Toronto 'This book will be of use to persons whose research interests include the subject matter of the book, but I also recommend sections of it more broadly... I strongly recommend the book for those who are involved in the field. It is very well written...' Ray L. Sweany, University of new Orleans in Journal of the American Chemical Society 'I strongly recommend the book for those who are involved in the field. It is very well written, and for those who are worried about the time delay between the onset of the writing and the publication, some references come from as late as the latter half of 2000' J.AM.Chem. Soc., 124:14 (2002)

Details ISBN0306464659 Author Gregory J. Kubas Series Modern Inorganic Chemistry Language English ISBN-10 0306464659 ISBN-13 9780306464652 Media Book Format Hardcover Year 2001 Publication Date 2001-08-31 Subtitle Structure, Theory and Reactivity Edition 1st Place of Publication New York Country of Publication United States Birth 1945 Edition Description 2001 Short Title METAL DIHYDROGEN & -BOND COMPL Pages 472 Imprint Kluwer Academic/Plenum Publishers DOI 10.1007/b113928;10.1007/978-0-306-47597-9 AU Release Date 2001-08-31 NZ Release Date 2001-08-31 US Release Date 2001-08-31 UK Release Date 2001-08-31 Publisher Springer Science+Business Media Alternative 9781475775389 DEWEY 541.2242 Illustrations XVI, 472 p. Audience Undergraduate

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TheNile_Item_ID:137568251;
  • Condition: Brand new
  • ISBN-13: 9780306464652
  • Book Title: Metal Dihydrogen and -Bond Complexes
  • ISBN: 9780306464652
  • Subject Area: Chemical Engineering
  • Publication Name: Metal Dihydrogen and -Bond Complexes
  • Publisher: Springer Science+Business Media
  • Subject: Chemistry
  • Publication Year: 2001
  • Type: Textbook
  • Format: Hardcover
  • Language: English
  • Item Height: 254mm
  • Author: Gregory J. Kubas
  • Item Width: 178mm
  • Item Weight: 2530g
  • Number of Pages: 472 Pages

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